Product ID:DZN 4E (DIAZINON)
MSDS Date:07/09/1987
FSC:6840
NIIN:00-782-3925
MSDS Number: BFPQP

CIBA-GEIGY CIRP, AGRICULTURAL DIV.

410 SWING ROAD
GREENSBORO, NC 27419
US

Emergency Phone: 800-888-8372 OR 800-334-9481

Cage: LO970

CIBA-GEIGY CORP, AGRICULTURAL DIV.

18300 GREENSBORO, NC 27419 US

Telephone: 800-888-8372 OR 800-334-9481

Cage: 8K340

AROMATIC PETROLEUM DERIVATIVE SOLVENT

DIAZINON (SARA III)

CAS: 333-41-5

RTECS: TF3325000

OSHA PEL S, 0.1 MG/M3

ACGIH TLV: S, 0.1 MG/M3; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TRIMETHYL BENZENE (SARA III)

CAS: 25551-13-7

RTECS: DC3220000

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT) 66 MG/KG, DIAZINON
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:CHRONIC: NO CHRONIC ADVERSE EFFECTS TO
HUMANS ARE KNOWN TO HAVE OCCURRED SINCE DIAZINON WAS INTRODUCED IN
1954. NOTES TO PHYSICIAN: DIAZINON IS AN ORGANOPHOSPKING CARE TO
PREVENT ASPIRATION OF STOMACH CONTENTS INTO LUNGS.
Effects of Overexposure:HEADACHE, GIDDINESS, BLURRED VISION, WEAKNESS,
NAUSEA, CRAMPS, DIARRHEA, DISCOMFORT IN THE CHEST, NERVOUSNESS,
SWEATING, MIOSIS(PINPONT PUPILS), TEARING, SALIVAL.

First Aid:INHALE:REMOVE TO FRESH AIR, IF BREATHING IS
DIFFICULT,ADMINISTER OXYGEN, IF BREATHING HAS STOPPED,APPLY
ARTIFICIAL RESPIRADTION; SKIN:WASH WITH SOAP & WATER ON THE
AFFECTED AREAS,REMOVE CONTAMINATED C 5 MINUTES; INGEST:DO NOT
INDUCE VOMITING. IF VICTIM IS FULLY CONSCIOUS, GIVE LARGE
QUANTITIES OF WATER TO DRINK. NOTHING FOR ANY UNCONSCIOUS PERSO

Flash Point Method:TCC
Flash Point:=46.1C, 115.F
115F/46.1C
Lower Limits:0.65
Upper Limits:5.4
Extinguishing Media:CO2,FOAM,DRY CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE STATED.

Spill Release Procedures:WEAR RUBBER GLOVES,BOOTS,SAFETY GOGGLES,
PROTECTIVE CLOTHING & HAT. COVERTHE SPILL WITH AN ABSORBENT
MATERIAL SUCH AS SWEEPING COMPOUND OR LIMP. SWEEP UP THE MATERIAL &
PLACE IN AN APPROPRIATE CHEMICA L WASTE CONTAINER.WASH THE SPILL
AREA WITH WATER.

Handling and Storage Precautions:DO NOT USE, POUR, OR STORE NEAR HEAT
OR OPNE FLAME. KEEP CONTAINER CLSD, USE W/ADEQ VENTIL. DO NOT REUSE
EMPTY CONTAINER. DESTROY & BURYING(MFR RECM
Other Precautions:MAY BE FATAL IF INGEST. MAY BE ABSORBED THROUGH THE
SKIN. DO NOT BRTH SPRAY MIST. DO NOT GET ON EYES,SKIN,CLOTHING.
WASH THROUGHLY AFTER HANDLING. AVOID CONTAM FOOD,FEED. KEEP FRM
ANIMALS/KIDS

Respiratory Protection:IF EXPOSED TO MIST OR SPRAY COULD OCCUR, WEAR AN
APPROVED PESTICIDE RESPIRATOR.
Ventilation:USE ADEQUATE VENTILATION.
Protective Gloves:RUBBER GLOVES
Eye Protection:CHEMICAL GOGGLES OR FACE SHIELD.
Other Protective Equipment:WATERPROOF BOOTS, IMPERIOUS CLOTHING AND
HAT.
Supplemental Safety and Health
% VOLATILE BY VOL: APPROX 10. MFR RECM MSA CONFO II PESTICIDE RESP IF
NEC. NOTE TO MD: ATROPINE IS ANTIDOTE IF USED EARLY & DOSE OF
DIAZINON NOT TOO GREAT. GIVE LG DOSES OF ATROPINE.

HCC:F5
Boiling Pt:B.P. Text:192 - 200C
Vapor Pres:0.5
Spec Gravity:1.02
Appearance and Odor:AMBER LIQUID, WITH SULFUR-LIKE ODOR

Stability Indicator/Materials to Avoid:YES
NONE STATED
Stability Condition to Avoid:AVOID STORAGE AT HIGH TEMP. PROTECT FROM
MOISTURE.
Hazardous Decomposition Products:VARIOUS ALIPHATIC ORGANOPHOSPHATES,
SUBSTITUTED PYRIMIDINES AND HYDROGEN CYANIDE.

Waste Disposal Methods:PLACE THE WASTE MATERIAL IN THE CHEMICAL WASTE
CONTAINER. SEAL CONTAINER & DISPOSE OF IN AN APPROVED MANNER. FLUSH
THE SPILL AREA WITH WATER TO REMOVE ANY WATER SUPPLIES. COMPLY WITH
FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.